Please use this identifier to cite or link to this item:
|Title:||Amperometric nitric oxide sensor based on nanoporous platinum phthalocyanine modified electrodes||Authors:||Yap, C.M.
|Issue Date:||2-Jan-2013||Citation:||Yap, C.M., Xu, G.Q., Ang, S.G. (2013-01-02). Amperometric nitric oxide sensor based on nanoporous platinum phthalocyanine modified electrodes. Analytical Chemistry 85 (1) : 107-113. ScholarBank@NUS Repository. https://doi.org/10.1021/ac302081h||Abstract:||This article describes the fabrication of electropolymerized Metallo 4′, 4″, 4ấ, 4′′′′ tetra-amine phthalocyanine (poly-MTAPc) modified electrodes for the detection of nitric oxide (NO) in phosphate-buffered saline (PBS) at pH 7.4. A two-step synthetic protocol using a laboratory microwave reactor was adopted to provide three MTAPc complexes bearing different metal centers (M = Cu2+: CuTAPc, M = Zn2+: ZnTAPc, and M = Pt2+: PtTAPc). The MTAPc complexes and the intermediates were characterized by MALDI-TOF mass spectrometry, UV-vis spectroscopy, 1H NMR spectroscopy, and elemental analysis. The MTAPc products were separately electropolymerized either onto a glassy carbon (GC) electrode as a thin-film or within the pores of Anodisc nanoporous alumina membrane as a densely packed array of poly-MTAPc nanotubes to produce two electrode systems. In the latter system, the surface area enhancement provided by the nanotube-arrayed morphology of the poly-MTAPc enabled a high faradaic (signal) to capacitative (background) current during NO electro-oxidation. Amperometric detection of NO using these two electrode systems shows that the sensitivity and linear ranges were insensitive to the metal centers (M = Cu 2+, Zn2+, and Pt2+) of the poly-MTAPc material. © 2012 American Chemical Society.||Source Title:||Analytical Chemistry||URI:||http://scholarbank.nus.edu.sg/handle/10635/93078||ISSN:||00032700||DOI:||10.1021/ac302081h|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Aug 4, 2020
WEB OF SCIENCETM
checked on Aug 4, 2020
checked on Aug 2, 2020
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.