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https://doi.org/10.1039/c3cc45202f
| Title: | Ambient arylmagnesiation of alkynes catalysed by ligandless nickel(ii) | Authors: | Xue, F. Zhao, J. Hor, T.S.A. |
Issue Date: | 7-Nov-2013 | Citation: | Xue, F., Zhao, J., Hor, T.S.A. (2013-11-07). Ambient arylmagnesiation of alkynes catalysed by ligandless nickel(ii). Chemical Communications 49 (86) : 10121-10123. ScholarBank@NUS Repository. https://doi.org/10.1039/c3cc45202f | Abstract: | A simple and efficient catalytic arylmagnesiation of diarylacetylenes and aryl(alkyl)acetylenes is accomplished by NiCl2·6H2O at r.t. in the absence of stabilising ligands. The corresponding tetra-substituted alkenes can be obtained in good yields by subsequent treatment with different electrophiles. © The Royal Society of Chemistry 2013. | Source Title: | Chemical Communications | URI: | http://scholarbank.nus.edu.sg/handle/10635/93073 | ISSN: | 13597345 | DOI: | 10.1039/c3cc45202f |
| Appears in Collections: | Staff Publications |
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