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Title: Ambient arylmagnesiation of alkynes catalysed by ligandless nickel(ii)
Authors: Xue, F. 
Zhao, J. 
Hor, T.S.A. 
Issue Date: 7-Nov-2013
Citation: Xue, F., Zhao, J., Hor, T.S.A. (2013-11-07). Ambient arylmagnesiation of alkynes catalysed by ligandless nickel(ii). Chemical Communications 49 (86) : 10121-10123. ScholarBank@NUS Repository.
Abstract: A simple and efficient catalytic arylmagnesiation of diarylacetylenes and aryl(alkyl)acetylenes is accomplished by NiCl2·6H2O at r.t. in the absence of stabilising ligands. The corresponding tetra-substituted alkenes can be obtained in good yields by subsequent treatment with different electrophiles. © The Royal Society of Chemistry 2013.
Source Title: Chemical Communications
ISSN: 13597345
DOI: 10.1039/c3cc45202f
Appears in Collections:Staff Publications

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