A strange nickel(I)-nickel(0) binuclear complex and its unexpected ethylene oligomerization

Please use this identifier to cite or link to this item: https://doi.org/10.1021/om0701322

Title:	A strange nickel(I)-nickel(0) binuclear complex and its unexpected ethylene oligomerization
Authors:	Weng, Z. Teo, S. Liu, Z.-P. Andy Hor, T.S.
Issue Date:	4-Jun-2007
Citation:	Weng, Z., Teo, S., Liu, Z.-P., Andy Hor, T.S. (2007-06-04). A strange nickel(I)-nickel(0) binuclear complex and its unexpected ethylene oligomerization. Organometallics 26 (12) : 2950-2952. ScholarBank@NUS Repository. https://doi.org/10.1021/om0701322
Abstract:	The unusual heterovalent bimetallic Ni1-Ni0 complex {[η-C5H4CH=N(C6F5)]Fe[η- C5H4PPh2]}2Ni2(Cl) (2) was isolated from the reaction between [η-C5H4CH= N(C6F5)]Fe[η-C5H4PPh 2] (1) and Ni(COD)2 in the presence of AlEtCl2 or AlCl3. Complex 2 has been crystallographically characterized and theoretically analyzed; it is catalytically active (TOF 90 500) and selective (91%) toward the formation of C4 oligomers from ethylene (300 psi) at 30 °C, the only other significant isomer formed being C6. © 2007 American Chemical Society.
Source Title:	Organometallics
URI:	http://scholarbank.nus.edu.sg/handle/10635/93012
ISSN:	02767333
DOI:	10.1021/om0701322
Appears in Collections:	Staff Publications

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