Please use this identifier to cite or link to this item:
https://doi.org/10.1002/chem.200902675
DC Field | Value | |
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dc.title | A cruciform 6, 6′-dipentacenyl: Synthesis, solid-state packing and applications in thin-film transistors | |
dc.contributor.author | Zhang, X. | |
dc.contributor.author | Jiang, X. | |
dc.contributor.author | Luo, J. | |
dc.contributor.author | Chi, C. | |
dc.contributor.author | Chen, H. | |
dc.contributor.author | Wu, J. | |
dc.date.accessioned | 2014-10-16T08:18:26Z | |
dc.date.available | 2014-10-16T08:18:26Z | |
dc.date.issued | 2010-01-11 | |
dc.identifier.citation | Zhang, X., Jiang, X., Luo, J., Chi, C., Chen, H., Wu, J. (2010-01-11). A cruciform 6, 6′-dipentacenyl: Synthesis, solid-state packing and applications in thin-film transistors. Chemistry - A European Journal 16 (2) : 464-468. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.200902675 | |
dc.identifier.issn | 09476539 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/92932 | |
dc.description.abstract | A novel molecular design concept 6,6'-linked pentacene dimer, 13,13'-bis(triisopropylsilylethynyl)-6,6'-dipentacenyl (Dips-TIPS) for high-performance organic semiconductors by using cruciform molecules as potential 2D isotropic charge transporting materials was reported. Dip-TIPS, exhibits the desired two-directional isotropic face-to-face π stacking, and FET mobilities of up to 0.11 cm2V-1s-1 were obtained based on vapor-deposited thin films. Dip-TIPS have good solubility in normal organic solvents, such as chloroform and THF. The absorption spectrum of Dip-TIPS in thin film displays an obvious bathochromic shift, which suggests that the molecules adopt a π-aggregated form in the solid state. The electrochemical properties of Dip-TIPS were investigated in CH 2Cl2, by using cyclic voltammetry. Differential scanning calorimetry (DSC) measurement of Dip-TIPS did not show any transitions below 350°C. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/chem.200902675 | |
dc.source | Scopus | |
dc.subject | Charge transfer | |
dc.subject | Field-effect transistors | |
dc.subject | Oligoacenes | |
dc.subject | Pi interactions | |
dc.subject | Semiconductors | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1002/chem.200902675 | |
dc.description.sourcetitle | Chemistry - A European Journal | |
dc.description.volume | 16 | |
dc.description.issue | 2 | |
dc.description.page | 464-468 | |
dc.description.coden | CEUJE | |
dc.identifier.isiut | 000274265100013 | |
Appears in Collections: | Staff Publications |
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