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Title: 4-Hydrazino-1-methyl-pyrazolo[3,4-d]pyrimidine
Authors: Dolzhenko, A.V. 
Pastorin, G. 
Dolzhenko, A.V. 
Tan, G.K.
Koh, L.L. 
Issue Date: 2009
Citation: Dolzhenko, A.V., Pastorin, G., Dolzhenko, A.V., Tan, G.K., Koh, L.L. (2009). 4-Hydrazino-1-methyl-pyrazolo[3,4-d]pyrimidine. Acta Crystallographica Section E: Structure Reports Online 65 (8) : o1720-o1721. ScholarBank@NUS Repository.
Abstract: The title compound, C6H8N6, crystallizes as an N - H⋯N hydrogen-bond-linked dimer of two almost identical mol-ecules in the asymmetric unit. Both of the mol-ecules are almost planar (rms deviations of 0.0186 and 0.0296 Å in the two molecules) and their hydrazino groups are turned towards the pyrazole rings. The dimers are arranged into chains via inter-molecular N - H⋯N hydrogen bonds between the hydrazino groups and the N atoms of the pyrimidine rings of both types of the mol-ecules, linking the mol-ecules into a C(7) graph-set motif along [100]. The methyl groups and the N atoms of the pyrazole rings form weak C - H⋯N hydrogen bonds, which connect chains of the dimers in a C(4) motif parallel to [100]. © 2009 Dolzhenko et al.
Source Title: Acta Crystallographica Section E: Structure Reports Online
ISSN: 16005368
DOI: 10.1107/S1600536809023952
Appears in Collections:Staff Publications

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