Please use this identifier to cite or link to this item:;2-0
Title: Rhodium tetracarbonyl hydride: The elusive metal carbonyl hydride
Authors: Li, C.
Widjaja, E.
Chew, W.
Garland, M. 
Keywords: Carbonyl complexes
IR spectroscopy
Issue Date: 18-Oct-2002
Citation: Li, C.,Widjaja, E.,Chew, W.,Garland, M. (2002-10-18). Rhodium tetracarbonyl hydride: The elusive metal carbonyl hydride. Angewandte Chemie - International Edition 41 (20) : 3785-3789. ScholarBank@NUS Repository.;2-0
Abstract: The pure-component spectra of [HRh(CO)4] and [DRh(CO)4] were obtained by investigating solutions of [Rh4(CO)12] in n-hexane upon exposure to varying partial pressures of H2/CO and D2/CO. The in situ high-pressure FTIR spectra were measured and subjected to band-target entropy minimization (BTEM), an advanced signal processing technique (shown schematically).
Source Title: Angewandte Chemie - International Edition
ISSN: 14337851
DOI: 10.1002/1521-3773(20021018)41:203.0.CO;2-0
Appears in Collections:Staff Publications

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