Please use this identifier to cite or link to this item: https://doi.org/10.1002/pola.1989.080271313
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dc.titleSynthesis and characterization of electrically conducting polyaniline-TCNE complexes
dc.contributor.authorNeoh, K.G.
dc.contributor.authorKang, E.T.
dc.contributor.authorKhor, S.H.
dc.contributor.authorTan, K.L.
dc.date.accessioned2014-10-09T08:21:44Z
dc.date.available2014-10-09T08:21:44Z
dc.date.issued1989-12
dc.identifier.citationNeoh, K.G., Kang, E.T., Khor, S.H., Tan, K.L. (1989-12). Synthesis and characterization of electrically conducting polyaniline-TCNE complexes. Journal of Polymer Science, Part A: Polymer Chemistry 27 (13) : 4365-4374. ScholarBank@NUS Repository. https://doi.org/10.1002/pola.1989.080271313
dc.identifier.issn0887624X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/91742
dc.description.abstractPolyaniline-tetracyanoethylene (TCNE) complexes can be synthesized either from emeraldine base or emeraldine hydrochloride by a relatively simple method. The complexes demonstrate greater stability than the emeraldine hydrochloride at elevated temperatures and under high current densities. The electrical conductivity of the complexes synthesized from emeraldine base can be varied from < 10-6 to 0.2 S/cm by varying the amount of TCNE incorporated. The complexes synthesized from emeraldine hydrochloride are slightly more conductive than the starting emeraldine hydrochloride. In both types of complexes, it appears that electron transfer between the polyaniline and TCNE has occurred resulting in the formation of some positively charged polyaniline nitrogen and TCNE anions.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/pola.1989.080271313
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMICAL ENGINEERING
dc.contributor.departmentPHYSICS
dc.description.doi10.1002/pola.1989.080271313
dc.description.sourcetitleJournal of Polymer Science, Part A: Polymer Chemistry
dc.description.volume27
dc.description.issue13
dc.description.page4365-4374
dc.description.codenJPACE
dc.identifier.isiutA1989CE30900013
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