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https://doi.org/10.1016/0022-0728(96)04668-2
DC Field | Value | |
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dc.title | Metal-polymer interactions in the Ag+|poly-o-aminophenol system | |
dc.contributor.author | Zhang, A.Q. | |
dc.contributor.author | Cui, C.Q. | |
dc.contributor.author | Lee, J.Y. | |
dc.date.accessioned | 2014-10-09T08:19:33Z | |
dc.date.available | 2014-10-09T08:19:33Z | |
dc.date.issued | 1996-09-12 | |
dc.identifier.citation | Zhang, A.Q., Cui, C.Q., Lee, J.Y. (1996-09-12). Metal-polymer interactions in the Ag+|poly-o-aminophenol system. Journal of Electroanalytical Chemistry 413 (1-2) : 143-151. ScholarBank@NUS Repository. https://doi.org/10.1016/0022-0728(96)04668-2 | |
dc.identifier.issn | 00220728 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/91559 | |
dc.description.abstract | Like polyaniline (PAn), electrodeposited films of poly-o-aminophenol (POAP) of different thicknesses, and hence different oxidation states, were found to react differently with a 0.1 M aqueous solution of AgNO3. The interactions between Ag+ and POAP ranged from redox reactions in which the cations were reduced to the metallic form upon contact with the polymer, to a partial charge transfer between metal and polymer resulting in the formation of a metal-polymer complex. These two types of interaction predominated in thick and thin films respectively, and films of moderate thickness exhibited intermediate behaviour. The interactions are believed to originate from a silver-nitrogen linkage moderated by the presence of oxygen from the -OH group. As POAP is more resistant to electrochemical degradation and can take up four times as much silver as PAn through the metal-polymer interactions, practical applications may be developed to exploit such properties. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/0022-0728(96)04668-2 | |
dc.source | Scopus | |
dc.subject | Ag+-poly-o-aminophenol | |
dc.subject | Metal-polymer interactions | |
dc.type | Article | |
dc.contributor.department | CHEMICAL ENGINEERING | |
dc.contributor.department | INSTITUTE OF MICROELECTRONICS | |
dc.description.doi | 10.1016/0022-0728(96)04668-2 | |
dc.description.sourcetitle | Journal of Electroanalytical Chemistry | |
dc.description.volume | 413 | |
dc.description.issue | 1-2 | |
dc.description.page | 143-151 | |
dc.description.coden | JECHE | |
dc.identifier.isiut | A1996VL46700017 | |
Appears in Collections: | Staff Publications |
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