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|Title:||Characterization of electrodeposited copolymers of aniline and metanilic acid||Authors:||Lee, J.Y.
|Issue Date:||4-Mar-1994||Citation:||Lee, J.Y.,Su, X.H.,Cui, C.Q. (1994-03-04). Characterization of electrodeposited copolymers of aniline and metanilic acid. Journal of Electroanalytical Chemistry 367 (1-2) : 71-78. ScholarBank@NUS Repository.||Abstract:||Copolymers of metanilic acid (MA) and aniline (An) deposited from different ratios of the monomers in 0.1 M H2SO4 were characterized by elemental analysis, Fourier transform IR spectroscopy, UV-visible spectroscopy, cyclic voltammetry and scanning electron microscopy. The presence of a polyaniline (PAn)-like structure in the copolymers was ascertained, although the copolymers possessed distinctly different morphologies and electrochemical behaviour in mineral acids. The copolymers were doped intramolecularly ("self-doping") by the sulfphonate functional group of MA and intermolecularly by the electrolyte anions. The total doping seemed to be limited to 50% but the extent of intramolecular doping versus intermolecular doping could be changed by adjusting the MA/An ratio in the starting mixture. © 1994.||Source Title:||Journal of Electroanalytical Chemistry||URI:||http://scholarbank.nus.edu.sg/handle/10635/91413||ISSN:||00220728|
|Appears in Collections:||Staff Publications|
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