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Title: Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities
Authors: Leong, W.L.J.
Garland, M.V. 
Yoong Goh, L. 
Kee Leong, W. 
Keywords: Cyclopentadienyl
Tethered functionalities
Issue Date: 20-Apr-2009
Citation: Leong, W.L.J., Garland, M.V., Yoong Goh, L., Kee Leong, W. (2009-04-20). Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities. Inorganica Chimica Acta 362 (6) : 2089-2092. ScholarBank@NUS Repository.
Abstract: The reaction of [C5H4(CH2)nX]Tl (1: n = 2, X = NMe2, OMe, CN; n = 3, X = NMe2) with [(η6-C6H6)RuCl(μ-Cl)]2, 2, afforded the sandwich compounds [{η5-C5H4(CH2)nX}Ru(η6-C6H6)]PF6, 3, and [η5-C5H4(CH2)nX]2Ru, 4. Photolytic cleavage of 3 in acetonitrile afforded the tethered products [{η5:κN-C5H4(CH2)nX}Ru(CH3CN)2]PF6, 5. © 2008 Elsevier B.V. All rights reserved.
Source Title: Inorganica Chimica Acta
ISSN: 00201693
DOI: 10.1016/j.ica.2008.09.026
Appears in Collections:Staff Publications

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