Please use this identifier to cite or link to this item:
|Title:||Resist-free micropatterning of binary polymer brushes on Si(100) via surface-initiated living radical polymerizations||Authors:||Xu, F.J.
|Issue Date:||2006||Citation:||Xu, F.J., Kang, E.T., Neoh, K.G. (2006). Resist-free micropatterning of binary polymer brushes on Si(100) via surface-initiated living radical polymerizations. Journal of Materials Chemistry 16 (28) : 2948-2952. ScholarBank@NUS Repository.||Abstract:||Binary polymer brushes were micropatterned, with the aid of a photomask and in the absence of any microlithographic resist, on Si(100) via consecutive surface-initiated atom transfer radical polymerization (ATRP) and reversible addition-fragmentation chain-transfer polymerization (RAFTP). The ATRP initiator was first micropatterned onto the hydrogen-terminated Si(100) surface via UV-induced hydrosilylation through a photomask. The azo initiator for RAFTP was coupled to the unhydrosilylated and re-oxidized microdomains. The orthogonal surface chemistries, that resulted after the single photochemical reaction step, allowed the spatially controlled immobilization of binary polymer brushes on an oriented single crystal silicon surface. © The Royal Society of Chemistry 2006.||Source Title:||Journal of Materials Chemistry||URI:||http://scholarbank.nus.edu.sg/handle/10635/90028||ISSN:||09599428|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Mar 7, 2018
WEB OF SCIENCETM
checked on Dec 19, 2018
checked on Oct 12, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.