Please use this identifier to cite or link to this item: https://doi.org/10.1021/jp077068m
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dc.titleParticle size effects in Pd-catalyzed electrooxidation of formic acid
dc.contributor.authorZhou, W.
dc.contributor.authorLee, J.Y.
dc.date.accessioned2014-10-09T06:57:06Z
dc.date.available2014-10-09T06:57:06Z
dc.date.issued2008-03-13
dc.identifier.citationZhou, W., Lee, J.Y. (2008-03-13). Particle size effects in Pd-catalyzed electrooxidation of formic acid. Journal of Physical Chemistry C 112 (10) : 3789-3793. ScholarBank@NUS Repository. https://doi.org/10.1021/jp077068m
dc.identifier.issn19327447
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/89727
dc.description.abstractSmall carbon-supported Pd nanoparticles with controllable size (2.7-9.0 nm) were prepared by a solution chemistry method, characterized by transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopies, and evaluated as anode catalysts for the electrooxidation of formic acid at room temperature. Measurements of catalytic activity by electrochemical methods (cyclic voltammetry and chronoamperometry) revealed a strong potential-dependent particle size effect. Classical volcano plots of catalytic activity vs particle size were obtained from which the optimal Pd particle size for the respective potential region was determined. © 2008 American Chemical Society.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/jp077068m
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMICAL & BIOMOLECULAR ENGINEERING
dc.description.doi10.1021/jp077068m
dc.description.sourcetitleJournal of Physical Chemistry C
dc.description.volume112
dc.description.issue10
dc.description.page3789-3793
dc.identifier.isiut000253784400046
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