Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jcat.2010.08.018
Title: Carbon monoxide-free hydrogen production via low-temperature steam reforming of ethanol over iron-promoted Rh catalyst
Authors: Chen, L.
Choong, C.K.S.
Zhong, Z.
Huang, L.
Ang, T.P.
Hong, L. 
Lin, J.
Keywords: Hydrogen production
Iron promotion
Rh catalyst
Steam reforming of ethanol
Issue Date: 15-Dec-2010
Citation: Chen, L., Choong, C.K.S., Zhong, Z., Huang, L., Ang, T.P., Hong, L., Lin, J. (2010-12-15). Carbon monoxide-free hydrogen production via low-temperature steam reforming of ethanol over iron-promoted Rh catalyst. Journal of Catalysis 276 (2) : 197-200. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jcat.2010.08.018
Abstract: For the first time, a novel iron-promoted Rh catalyst is developed to produce CO-free H2 through steam reforming of ethanol at low temperatures, between 623 and 673 K. The iron oxides in the vicinity of Rh sites reduce the CO adsorption on Rh sites and transfer the adsorbed CO from Rh to COO-formate species on FexOy for the subsequent water-gas shift reaction, resulting in a high H2 yield, extremely low CO selectivity, and a long Rh life span. © 2010 Elsevier Inc. All rights reserved.
Source Title: Journal of Catalysis
URI: http://scholarbank.nus.edu.sg/handle/10635/88609
ISSN: 00219517
DOI: 10.1016/j.jcat.2010.08.018
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