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Title: Armored MOFs: Enforcing soft microporous MOF nanocrystals with hard mesoporous silica
Authors: Li, Z.
Zeng, H.C. 
Issue Date: 16-Apr-2014
Citation: Li, Z., Zeng, H.C. (2014-04-16). Armored MOFs: Enforcing soft microporous MOF nanocrystals with hard mesoporous silica. Journal of the American Chemical Society 136 (15) : 5631-5639. ScholarBank@NUS Repository.
Abstract: Metal-organic frameworks (MOFs) are a class of fascinating supramolecular soft matters but with relatively weak mechanical strength. To enforce MOF materials for practical applications, one possible way seems to be transforming them into harder composites with a stronger secondary phase. Apparently, such a reinforcing phase must possess larger porosity for ionic or molecular species to travel into or out of MOFs without altering their pristine physicochemical properties. Herein we report a general synthetic approach to coat microporous MOFs and their derivatives with an enforcing shell of mesoporous silica (mSiO2). Four well-known MOFs (ZIF-8, ZIF-7, UiO-66, and HKUST-1), representing two important families of MOFs, have served as a core phase in nanocomposite products. We show that significant enhancement in mechanical properties (hardness and toughness) can indeed be achieved with this "armoring approach". Excellent accessibility of the mSiO 2-wrapped MOFs and their metal-containing nanocomposites has also been demonstrated with catalytic reduction of 4-nitrophenol. © 2014 American Chemical Society.
Source Title: Journal of the American Chemical Society
ISSN: 15205126
DOI: 10.1021/ja409675j
Appears in Collections:Staff Publications

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