Please use this identifier to cite or link to this item: https://doi.org/10.1038/srep01149
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dc.titleA rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability
dc.contributor.authorWang, X.-J.
dc.contributor.authorLi, P.-Z.
dc.contributor.authorChen, Y.
dc.contributor.authorZhang, Q.
dc.contributor.authorZhang, H.
dc.contributor.authorChan, X.X.
dc.contributor.authorGanguly, R.
dc.contributor.authorLi, Y.
dc.contributor.authorJiang, J.
dc.contributor.authorZhao, Y.
dc.date.accessioned2014-10-09T06:42:44Z
dc.date.available2014-10-09T06:42:44Z
dc.date.issued2013
dc.identifier.citationWang, X.-J., Li, P.-Z., Chen, Y., Zhang, Q., Zhang, H., Chan, X.X., Ganguly, R., Li, Y., Jiang, J., Zhao, Y. (2013). A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability. Scientific Reports 3 : -. ScholarBank@NUS Repository. https://doi.org/10.1038/srep01149
dc.identifier.issn20452322
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/88474
dc.description.abstractOn the way towards a sustainable low-carbon future, the design and construction of chemical or physical adsorbents for CO2 capture and clean energy storage are vital technology. The incorporation of accessible nitrogen-donor sites into the pore walls of porous adsorbents can dramatically affect the CO2 uptake capacity and selectivity on account of the dipole-quadrupole interactions between the polarizable CO2 molecule and the accessible nitrogen site. In the present work, a nitrogen-rich rth-type metal-organic framework (MOF) was constructed based on rational design and careful synthesis. The MOF presents exceptionally high uptake capacity not only for CO2 but also for H 2, which is attributed to favorable interactions between the gas molecules and the nitrogen-rich triazole units of the MOF proved by both experimental measurements and theoretical molecular simulations.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1038/srep01149
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMICAL & BIOMOLECULAR ENGINEERING
dc.description.doi10.1038/srep01149
dc.description.sourcetitleScientific Reports
dc.description.volume3
dc.description.page-
dc.identifier.isiut000314356900004
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