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dc.titleA rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability
dc.contributor.authorWang, X.-J.
dc.contributor.authorLi, P.-Z.
dc.contributor.authorChen, Y.
dc.contributor.authorZhang, Q.
dc.contributor.authorZhang, H.
dc.contributor.authorChan, X.X.
dc.contributor.authorGanguly, R.
dc.contributor.authorLi, Y.
dc.contributor.authorJiang, J.
dc.contributor.authorZhao, Y.
dc.identifier.citationWang, X.-J., Li, P.-Z., Chen, Y., Zhang, Q., Zhang, H., Chan, X.X., Ganguly, R., Li, Y., Jiang, J., Zhao, Y. (2013). A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability. Scientific Reports 3 : -. ScholarBank@NUS Repository.
dc.description.abstractOn the way towards a sustainable low-carbon future, the design and construction of chemical or physical adsorbents for CO2 capture and clean energy storage are vital technology. The incorporation of accessible nitrogen-donor sites into the pore walls of porous adsorbents can dramatically affect the CO2 uptake capacity and selectivity on account of the dipole-quadrupole interactions between the polarizable CO2 molecule and the accessible nitrogen site. In the present work, a nitrogen-rich rth-type metal-organic framework (MOF) was constructed based on rational design and careful synthesis. The MOF presents exceptionally high uptake capacity not only for CO2 but also for H 2, which is attributed to favorable interactions between the gas molecules and the nitrogen-rich triazole units of the MOF proved by both experimental measurements and theoretical molecular simulations.
dc.description.sourcetitleScientific Reports
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