Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.cej.2009.05.029
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dc.titleRemoval of copper by calcium alginate encapsulated magnetic sorbent
dc.contributor.authorLim, S.-F.
dc.contributor.authorZheng, Y.-M.
dc.contributor.authorZou, S.-W.
dc.contributor.authorChen, J.P.
dc.date.accessioned2014-10-08T08:33:38Z
dc.date.available2014-10-08T08:33:38Z
dc.date.issued2009-10-15
dc.identifier.citationLim, S.-F., Zheng, Y.-M., Zou, S.-W., Chen, J.P. (2009-10-15). Removal of copper by calcium alginate encapsulated magnetic sorbent. Chemical Engineering Journal 152 (2-3) : 509-513. ScholarBank@NUS Repository. https://doi.org/10.1016/j.cej.2009.05.029
dc.identifier.issn13858947
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/87622
dc.description.abstractIn this study, the adsorption performance of copper on calcium alginate encapsulated magnetic sorbent is investigated via equilibrium and kinetics study. Results showed the sorption performance is greatly affected by the initial solution pH, the background ionic strength, the mechanical stirring speed, and the presence of humic acid. The optimum copper sorption was achieved at initial solution pH > 5. The copper uptake is poor in the presence of higher background ionic strength (sodium perchlorate). Langmuir equation can be well used to describe the adsorption isotherm data. The maximum sorption capacity (qmax) and Langmuir constant (b) decrease from 60 to 49 mg g-1 and 1.43 to 0.35 L mg-1 as the ionic strength is increased from 0 to 0.05 M. Kinetics study shows the sorption equilibrium can be obtained within 3 h, and the adsorption kinetics data are well described by the intraparticle pore diffusion model. The mechanical stirring speed greatly enhances the mass transfer rate of copper ions onto the sorbent, and the external mass transfer coefficient (kf) increases from 2.5 × 10-5 to 2.5 × 10-4 m s-1 when stirring speed is increased from 120 to 220 rpm. The presence of humic acid decreases the kf from 2.10 × 10-4 to 5 × 10-5 m s-1, and increases the time for copper to attain adsorption equilibrium due to clogging of surface pore which apparently reduce the surface reaction site. © 2009 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.cej.2009.05.029
dc.sourceScopus
dc.subjectCalcium alginate encapsulated magnetic sorbent
dc.subjectCopper sorption
dc.subjectEquilibrium
dc.subjectKinetics
dc.subjectModeling
dc.typeArticle
dc.contributor.departmentDIVISION OF ENVIRONMENTAL SCIENCE & ENGG
dc.description.doi10.1016/j.cej.2009.05.029
dc.description.sourcetitleChemical Engineering Journal
dc.description.volume152
dc.description.issue2-3
dc.description.page509-513
dc.description.codenCMEJA
dc.identifier.isiut000274348500028
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