Please use this identifier to cite or link to this item:
|Title:||Polyanion conduction mechanism in solid scandium tungstate||Authors:||Zhou, Y.
|Issue Date:||2009||Citation:||Zhou, Y.,Adams, S.N.,Neiman, A. (2009). Polyanion conduction mechanism in solid scandium tungstate. Materials Research Society Symposium Proceedings 1177 : 74-80. ScholarBank@NUS Repository.||Abstract:||Scandium tungstate is investigated as a model material for solid electrolytes in which polyatomic anions, here WO4 2-, are mobile in the solid state. Simulations using structures with artificially induced WO4 2- vacancy, Frenkel defect and Schottky defects produced lower activation energy compared to the initially defect-free model. Simulations with Frenkel defect structures show low activation energy but the interstitial WO4 2- has initially a strong preference to return to the vacant tungstate site. The vacancy defect model reproduces the activation energy to the experimental conductivity studies more closely. Qualitative considerations support the idea that vacancies formed during the sample preparation are the most abundant mobile defect among the investigated cases. Nonstoichiometric samples with varying initial Sc2O 3:WO3 ratios SC2O3 - xWO 3, where x = 2.9, 3.0 and 3.1, are synthesized and characterized by XRD and impedance measurements, but a significant influence on the conductivity could not be confirmed experimentally. © 2009 Materials Research Society.||Source Title:||Materials Research Society Symposium Proceedings||URI:||http://scholarbank.nus.edu.sg/handle/10635/86948||ISBN:||9781617383960||ISSN:||02729172|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Aug 17, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.