Please use this identifier to cite or link to this item:
|Title:||Organic molecules based on dithienyl-2,1,3-benzothiadiazole as new donor materials for solution-processed organic photovoltaic cells||Authors:||Wu, Z.
Organic solar cells
Sonogashira coupling reaction
|Issue Date:||Dec-2010||Citation:||Wu, Z., Fan, B., Xue, F., Adachi, C., Ouyang, J. (2010-12). Organic molecules based on dithienyl-2,1,3-benzothiadiazole as new donor materials for solution-processed organic photovoltaic cells. Solar Energy Materials and Solar Cells 94 (12) : 2230-2237. ScholarBank@NUS Repository. https://doi.org/10.1016/j.solmat.2010.07.017||Abstract:||Polymers based on dithienyl-2,1,3-benzothiadiazole (TBT) have received strong attention as the donor materials of polymer photovoltaic cells (PVs), since they can have a low band gap. But soluble small organic molecules based on TBT have been rarely studied. This paper reports the synthesis of two small organic molecules based on TBT and their application as the donor materials of solution-processed bulk heterojunction organic photovoltaic cells (OPVs). These compounds were soluble in common organic solvents, such as chloroform, chlorobenzene and tetrahydrofuran. They have band gaps comparable to poly(3-hexylthiophene) (P3HT) and lower HOMO and LUMO (HOMO: highest occupied molecular orbital, LUMO: lowest unoccupied molecular orbital) levels than P3HT. These molecules and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) were used as the donors and acceptor to fabricate bulk heterojunction OPVs through solution processing. After optimization of the experimental conditions, power conversion efficiency (PCE) of 0.66% was achieved on the solution-processed OPVs under AM 1.5G, 100 mW cm-2 illumination. © 2010 Elsevier B.V. All rights reserved.||Source Title:||Solar Energy Materials and Solar Cells||URI:||http://scholarbank.nus.edu.sg/handle/10635/86617||ISSN:||09270248||DOI:||10.1016/j.solmat.2010.07.017|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.