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|Title:||Nanostructured electrode materials for Li-ion battery||Authors:||Balaya, P.
high rate performance
|Issue Date:||2010||Citation:||Balaya, P., Saravanan, K., Hariharan, S. (2010). Nanostructured electrode materials for Li-ion battery. Proceedings of SPIE - The International Society for Optical Engineering 7683 : -. ScholarBank@NUS Repository. https://doi.org/10.1117/12.849797||Abstract:||Nanostructured materials have triggered a great excitement in recent times due to both fundamental interest as well as technological impact relevant for lithium ion batteries (LIBs). Size reduction in nanocrystals leads to a variety of unexpected exciting phenomena due to enhanced surface-to-volume ratio and reduced transport length. We will consider a few examples of nanostructured electrode materials in the context of lithium batteries for achieving high storage and high rate performances: 1) LiFePO4 nanoplates synthesized using solvothermal method could store Li-ions comparable to its theoretical capacity at C/10, while at 30C, they exhibit storage capacity up to 45 mAh/g. Size reduction (~30 nm) at the b-axis favors the fast Li-ion diffusion. In addition to this, uniform ~5 nm carbon coating throughout the plates provides excellent electronically conducting path for electrons. This nano architecture enables fast insertion/extraction of both Li-ions as well as electrons; 2) Mesporous-TiO2 with high surface area (135m2/g) synthesized using soft-template method exhibits high volumetric density compared to commercial nanopowder (P25), with excellent Li-storage behavior. C16 meso-TiO2 synthesized from CTAB exhibits reversible storage capacity of 288mAh/g at 0.2C and 109 mAh/g at 30C; 3) Zero strain Li4Ti 5O12 anode material has been synthesized using several wet chemical routes. The best condition has been optimized to achieve storage capability close to theoretical limit of 175mAh/g at C/10. At 10C, we could retain lithium storage up to 88 mAh/g; 4) We report our recent results on α-Fe2O3 and γ-Fe2O3 using conversion reaction, providing insight for a better storage capability in γ-phase than the α-phase at 2C resulting solely from the nanocrystallinity. © 2010 Copyright SPIE - The International Society for Optical Engineering.||Source Title:||Proceedings of SPIE - The International Society for Optical Engineering||URI:||http://scholarbank.nus.edu.sg/handle/10635/86038||ISBN:||9780819481474||ISSN:||0277786X||DOI:||10.1117/12.849797|
|Appears in Collections:||Staff Publications|
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