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|Title:||Improved capacitive behavior of MnO 2 thin films prepared by electrodeposition on the PT substrate with a MnO x buffer layer||Authors:||Xia, H.
|Issue Date:||Mar-2009||Citation:||Xia, H., Xiao, W., Lai, M.O., Lu, L. (2009-03). Improved capacitive behavior of MnO 2 thin films prepared by electrodeposition on the PT substrate with a MnO x buffer layer. Functional Materials Letters 2 (1) : 13-18. ScholarBank@NUS Repository. https://doi.org/10.1142/S1793604709000478||Abstract:||Nanostructured MnO 2 thin films were prepared on two types of substrates, Pt/Ti/SiO 2/Si (PT) and MnO x/Pt/Ti/SiO 2/Si (MnO x/PT), by the technique of cyclic-voltammetric electrodeposition. The MnO x buffer layer was deposited on the PT substrate by pulsed laser deposition (PLD). The as-deposited MnO 2 thin films were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and X-ray photoelectron spectroscopy (XPS). The electrochemical properties of the thin film MnO 2 electrodes were investigated using cyclic voltammetry (CV) in 1 M Na 2SO 4 electrolyte. It was found that the adhesion between the MnO 2 film and the Pt substrate was poor, resulting in cracks and peeling of the MnO 2 film after deposition. However, the adhesion of the MnO 2 film with the MnO x buffer layer was greatly improved, resulting in superior pseudocapacitive performance of the thin film electrodes. A specific capacitance of about 364 F/g of MnO 2 thin films deposited on the MnO x buffer layer can be obtained at a scan rate of 10 mV/s in the voltage window between 0 and 0.9 V versus the Ag/AgCl reference electrode. The MnO 2 thin film deposited on the MnO x/PT substrate exhibits good rate capability and excellent cycle performance, which makes it promising for supercapacitor application. © 2009 World Scientific Publishing Company.||Source Title:||Functional Materials Letters||URI:||http://scholarbank.nus.edu.sg/handle/10635/85291||ISSN:||17936047||DOI:||10.1142/S1793604709000478|
|Appears in Collections:||Staff Publications|
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