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https://doi.org/10.1016/j.inoche.2004.01.014
| Title: | Crystallographic characterization of the intermediate in the synthesis of tetrazole from nitrile and azide in water | Authors: | Yu, Z. Wang, X. Feng, Y. Zhong, X. |
Keywords: | Crystal structure Cycloaddition Tetrazole Zinc |
Issue Date: | Apr-2004 | Citation: | Yu, Z., Wang, X., Feng, Y., Zhong, X. (2004-04). Crystallographic characterization of the intermediate in the synthesis of tetrazole from nitrile and azide in water. Inorganic Chemistry Communications 7 (4) : 492-494. ScholarBank@NUS Repository. https://doi.org/10.1016/j.inoche.2004.01.014 | Abstract: | The intermediate [Zn(4-PTZ)2(H2O)4] (4-PTZ=5-(4-pyridyl N-oxide)tetrazolate) (1) in the synthesis of 4-H-PTZ (2) from cycloaddition reaction of 4-cyanopyridine N-oxide with NaN3 in water catalyzed by ZnCl2 was structurally characterized. The catalysis role of Zn2+ in the synthesis of tetrazole stems from the formation of tetrazolate zinc complex 1. © 2004 Elsevier B.V. All rights reserved. | Source Title: | Inorganic Chemistry Communications | URI: | http://scholarbank.nus.edu.sg/handle/10635/84552 | ISSN: | 13877003 | DOI: | 10.1016/j.inoche.2004.01.014 |
| Appears in Collections: | Staff Publications |
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