Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.inoche.2004.01.014
Title: Crystallographic characterization of the intermediate in the synthesis of tetrazole from nitrile and azide in water
Authors: Yu, Z.
Wang, X.
Feng, Y. 
Zhong, X. 
Keywords: Crystal structure
Cycloaddition
Tetrazole
Zinc
Issue Date: Apr-2004
Citation: Yu, Z., Wang, X., Feng, Y., Zhong, X. (2004-04). Crystallographic characterization of the intermediate in the synthesis of tetrazole from nitrile and azide in water. Inorganic Chemistry Communications 7 (4) : 492-494. ScholarBank@NUS Repository. https://doi.org/10.1016/j.inoche.2004.01.014
Abstract: The intermediate [Zn(4-PTZ)2(H2O)4] (4-PTZ=5-(4-pyridyl N-oxide)tetrazolate) (1) in the synthesis of 4-H-PTZ (2) from cycloaddition reaction of 4-cyanopyridine N-oxide with NaN3 in water catalyzed by ZnCl2 was structurally characterized. The catalysis role of Zn2+ in the synthesis of tetrazole stems from the formation of tetrazolate zinc complex 1. © 2004 Elsevier B.V. All rights reserved.
Source Title: Inorganic Chemistry Communications
URI: http://scholarbank.nus.edu.sg/handle/10635/84552
ISSN: 13877003
DOI: 10.1016/j.inoche.2004.01.014
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.