Please use this identifier to cite or link to this item:
|Title:||Catalytic decarboxylative reactions: Biomimetic approaches inspired by polyketide biosynthesis||Authors:||Pan, Y.
malonic acid half thioester
|Issue Date:||2011||Citation:||Pan, Y., Tan, C.-H. (2011). Catalytic decarboxylative reactions: Biomimetic approaches inspired by polyketide biosynthesis. Synthesis (13) : 2044-2053. ScholarBank@NUS Repository. https://doi.org/10.1055/s-0030-1260607||Abstract:||This short review summarizes decarboxylative reactions of malonic acid half thio/oxyester mediated by metal complexes and organocatalysts. These biomimetic reactions are inspired by similar reactions catalyzed by polyketide synthase. While they have been known for several decades, this is the first review of these reactions. 1 Introduction 2 Decarboxylative Reactions Catalyzed by Metal Complexes 2.1 Condensation Reaction 2.2 Aldol Reaction 2.3 1,4-Addition 3 Organocatalytic Decarboxylative Reactions 3.1 Condensation Reaction 3.2 Aldol Reaction 3.3 1,4-Addition 3.4 Mannich Reaction 3.5 Amination Reaction 3.6 Protonation 4 Conclusion © Georg Thieme Verlag Stuttgart • New York.||Source Title:||Synthesis||URI:||http://scholarbank.nus.edu.sg/handle/10635/77583||ISSN:||00397881||DOI:||10.1055/s-0030-1260607|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Apr 8, 2020
WEB OF SCIENCETM
checked on Mar 23, 2020
checked on Mar 30, 2020
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.