Please use this identifier to cite or link to this item: https://doi.org/10.1002/jrs.718
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dc.titleComplex Raman amplitude recovery and dynamics from the Raman excitation profile: Application to iodobenzene and azulene
dc.contributor.authorFeng, Z.W.
dc.contributor.authorLee, S.Y.
dc.date.accessioned2014-06-23T05:54:48Z
dc.date.available2014-06-23T05:54:48Z
dc.date.issued2001
dc.identifier.citationFeng, Z.W., Lee, S.Y. (2001). Complex Raman amplitude recovery and dynamics from the Raman excitation profile: Application to iodobenzene and azulene. Journal of Raman Spectroscopy 32 (6-7) : 447-459. ScholarBank@NUS Repository. https://doi.org/10.1002/jrs.718
dc.identifier.issn03770486
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/77418
dc.description.abstractRecovering the complex amplitude or phase from an intensity, which is given as the modulus square of the amplitude, is a problem common to diverse physical areas. The focus of this paper is on the Raman excitation profile - the Raman intensity of a mode as a function of the excitation energy - which is given by the modulus square of the Raman amplitude. Three methods, with different principles, are presented for amplitude or phase recovery: the dispersion or energy-frame method; the z-transform or time-frame method; and the maximum entropy method. A comparison function technique is introduced to address the usual situation where the measured intensity is band-limited. There are two classes of problems, minimum phase and non-minimum phase, and the mapping from the intensity to the complex amplitude may not be unique. The non-minimum phase situation occurs when the analytically extended complex amplitude, with the energy E replaced by ξ = γ - iE, has zeros in the right-half complex plane. These zeros have implications for the system dynamics. An algorithm is presented to search for the critical zeros. The characteristics of the zeros are studied with a two-mode harmonic model, and the theory is applied to the Raman excitation profiles of iodobenzene and azulene. © 2001 John Wiley & Sons, Ltd.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/jrs.718
dc.sourceScopus
dc.typeConference Paper
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1002/jrs.718
dc.description.sourcetitleJournal of Raman Spectroscopy
dc.description.volume32
dc.description.issue6-7
dc.description.page447-459
dc.description.codenJRSPA
dc.identifier.isiut000170359700006
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