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https://doi.org/10.1021/ol0263999
Title: | The first example of enantioselective allyl transfer from a linear homoallylic alcohol to an aldehyde | Authors: | Loh, T.-P. Lee, C.-L.K. Tan, K.-T. |
Issue Date: | 22-Aug-2002 | Citation: | Loh, T.-P., Lee, C.-L.K., Tan, K.-T. (2002-08-22). The first example of enantioselective allyl transfer from a linear homoallylic alcohol to an aldehyde. Organic Letters 4 (17) : 2985-2987. ScholarBank@NUS Repository. https://doi.org/10.1021/ol0263999 | Abstract: | (Formula Presented) The first example of enantioselective linear homoallylic alcohol transfer reaction was revealed. In all cases, the whole rearrangement is thermodynamically favorable and a steric effect is the driving force of this reaction. The preservation of the stereocenter and olefin geometry together with the isolation of γ-adduct homoallylic alcohols in one isomeric form have warranted the proposed mechanism. | Source Title: | Organic Letters | URI: | http://scholarbank.nus.edu.sg/handle/10635/77239 | ISSN: | 15237060 | DOI: | 10.1021/ol0263999 |
Appears in Collections: | Staff Publications |
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