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|Title:||The first example of enantioselective allyl transfer from a linear homoallylic alcohol to an aldehyde||Authors:||Loh, T.-P.
|Issue Date:||22-Aug-2002||Citation:||Loh, T.-P., Lee, C.-L.K., Tan, K.-T. (2002-08-22). The first example of enantioselective allyl transfer from a linear homoallylic alcohol to an aldehyde. Organic Letters 4 (17) : 2985-2987. ScholarBank@NUS Repository. https://doi.org/10.1021/ol0263999||Abstract:||(Formula Presented) The first example of enantioselective linear homoallylic alcohol transfer reaction was revealed. In all cases, the whole rearrangement is thermodynamically favorable and a steric effect is the driving force of this reaction. The preservation of the stereocenter and olefin geometry together with the isolation of γ-adduct homoallylic alcohols in one isomeric form have warranted the proposed mechanism.||Source Title:||Organic Letters||URI:||http://scholarbank.nus.edu.sg/handle/10635/77239||ISSN:||15237060||DOI:||10.1021/ol0263999|
|Appears in Collections:||Staff Publications|
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