Please use this identifier to cite or link to this item: https://doi.org/10.1039/b918671a
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dc.titleSynthesis, physical properties and self-assembly of star-shaped oligothiophenes-substituted and fused triphenylenes
dc.contributor.authorLuo, J.
dc.contributor.authorZhao, B.
dc.contributor.authorOn Chan, H.S.
dc.contributor.authorChi, C.
dc.date.accessioned2014-06-23T05:52:03Z
dc.date.available2014-06-23T05:52:03Z
dc.date.issued2010
dc.identifier.citationLuo, J., Zhao, B., On Chan, H.S., Chi, C. (2010). Synthesis, physical properties and self-assembly of star-shaped oligothiophenes-substituted and fused triphenylenes. Journal of Materials Chemistry 20 (10) : 1932-1941. ScholarBank@NUS Repository. https://doi.org/10.1039/b918671a
dc.identifier.issn09599428
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/77196
dc.description.abstractA series of star-shaped oligothiophene-attached and fused triphenylenes was synthesized. The synthesis was first conducted by six-fold Pd-catalyzed Stille cross-coupling reactions to yield the hexakis-oligothiophenes substituted triphenylenes TTP, TTP1, TTP2 and TTP3 and then followed by successful oxidative cyclodehydrogenation of TTP1 to generate the thiophene-fused triphenylene compound TTP1-C with an extended core. Their optical, electrochemical, thermal properties and self-assembly behaviors were investigated and the structure-property relationships were established, which clearly demonstrated the influence of the length of the peripheral oligothiophene units and the core structure on the electronic nature and solid-state packing of these star-shaped disc-like molecules. © 2010 The Royal Society of Chemistry.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1039/b918671a
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1039/b918671a
dc.description.sourcetitleJournal of Materials Chemistry
dc.description.volume20
dc.description.issue10
dc.description.page1932-1941
dc.description.codenJMACE
dc.identifier.isiut000274920500014
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