Please use this identifier to cite or link to this item: https://doi.org/10.1021/cm703686w
DC FieldValue
dc.titleSuzuki coupling of aryl organics on diamond
dc.contributor.authorZhong, Y.L.
dc.contributor.authorLoh, K.P.
dc.contributor.authorMidya, A.
dc.contributor.authorChen, Z.-K.
dc.date.accessioned2014-06-23T05:51:09Z
dc.date.available2014-06-23T05:51:09Z
dc.date.issued2008-05-13
dc.identifier.citationZhong, Y.L., Loh, K.P., Midya, A., Chen, Z.-K. (2008-05-13). Suzuki coupling of aryl organics on diamond. Chemistry of Materials 20 (9) : 3137-3144. ScholarBank@NUS Repository. https://doi.org/10.1021/cm703686w
dc.identifier.issn08974756
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/77120
dc.description.abstractWe demonstrate a facile method for the Suzuki coupling of aryl molecules on the diamond surface. This is a more versatile alternative compared to previous coupling methods based on alkene linkers because it opens up possibilities for the application of diamond in molecular electronics and photovoltaics. The diamond surface is premodified with aryldiazonium salt in order to functionalize it with aryl halide or aryl boronic acid, and these are then used as synthons in the subsequent Suzuki coupling to aryl molecules. This method is highly specific and can be used for the uninterrupted molecular conjugation of diamond to a large class of organic molecules. As a proof of concept, we also demonstrate a diamond-fullerene photocurrent converter by using Suzuki coupled oligothiophene as the conjugated linker between diamond (electron donor) and fullerene (electron acceptor). © 2008 American Chemical Society.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/cm703686w
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1021/cm703686w
dc.description.sourcetitleChemistry of Materials
dc.description.volume20
dc.description.issue9
dc.description.page3137-3144
dc.description.codenCMATE
dc.identifier.isiut000255623400050
Appears in Collections:Staff Publications

Show simple item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

44
checked on Dec 3, 2019

WEB OF SCIENCETM
Citations

39
checked on Dec 3, 2019

Page view(s)

80
checked on Dec 1, 2019

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.