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https://doi.org/10.1039/b411653d
| Title: | Silicon-assisted propargylic transfer to aldehydes | Authors: | Lee, K.-C. Lin, M.-J. Loh, T.-P. |
Issue Date: | 7-Nov-2004 | Citation: | Lee, K.-C., Lin, M.-J., Loh, T.-P. (2004-11-07). Silicon-assisted propargylic transfer to aldehydes. Chemical Communications 10 (21) : 2456-2457. ScholarBank@NUS Repository. https://doi.org/10.1039/b411653d | Abstract: | A new and efficient method of obtaining homopropargylic alcohols via homopropargylic transfer from the allenic alcohol to various aldehydes in the presence of Lewis acid catalysts is described; stereochemical studies have shown that this process is the first oxonium [3,3]-sigmatropic rearrangement of an allenic alcohol to a homopropargylic alcohol in the presence of aldehydes and Lewis acid. | Source Title: | Chemical Communications | URI: | http://scholarbank.nus.edu.sg/handle/10635/76968 | ISSN: | 13597345 | DOI: | 10.1039/b411653d |
| Appears in Collections: | Staff Publications |
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