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|Title:||Palladium-complex-promoted asymmetric Diels-Alder reaction: Stereoselective synthesis of a new sulfinyl-substituted phosphine ligand containing three carbon, one phosphorus and one sulfur stereogenic centres||Authors:||Siah, S.-Y.
|Issue Date:||1995||Citation:||Siah, S.-Y., Leung, P.-H., Mok, K.F. (1995). Palladium-complex-promoted asymmetric Diels-Alder reaction: Stereoselective synthesis of a new sulfinyl-substituted phosphine ligand containing three carbon, one phosphorus and one sulfur stereogenic centres. Journal of the Chemical Society, Chemical Communications (17) : 1747-1748. ScholarBank@NUS Repository. https://doi.org/10.1039/C39950001747||Abstract:||Palladium(II) complexes derived from the optically active forms of N,N-dimethyl-1-(1-naphthyl)ethylamine are efficient promoters for the asymmetric Diels-Alder reaction between 1-phenyl-3,4-dimethylphosphole and divinyl sulfoxide; the absolute configurations of the five newly generated chiral centres in this cycloaddition reaction were determined by a crystal structural analysis of a product complex.||Source Title:||Journal of the Chemical Society, Chemical Communications||URI:||http://scholarbank.nus.edu.sg/handle/10635/76722||ISSN:||00224936||DOI:||10.1039/C39950001747|
|Appears in Collections:||Staff Publications|
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