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|Title:||Open-shell polycyclic aromatic hydrocarbons||Authors:||Sun, Z.
|Issue Date:||14-Mar-2012||Citation:||Sun, Z., Wu, J. (2012-03-14). Open-shell polycyclic aromatic hydrocarbons. Journal of Materials Chemistry 22 (10) : 4151-4160. ScholarBank@NUS Repository. https://doi.org/10.1039/c1jm14786b||Abstract:||Polycyclic aromatic hydrocarbons (PAHs) with unpaired or partially unpaired electrons will display open-shell radical character (monoradical, biradical, polyradical). This will lead to special features in electronic structures, magnetic properties and crystalline packing, which endow them with great potential as a new generation of materials. Stability issues are always the focus on the way towards functionalized open-shell PAHs, and chemists have made huge endeavours in synthesizing stable PAHs with open-shell characters. In this article, we summarize recent developments on open-shell PAHs covering both theoretical advances and experimental progresses, and touch on a few examples of them for practical applications. © 2012 The Royal Society of Chemistry.||Source Title:||Journal of Materials Chemistry||URI:||http://scholarbank.nus.edu.sg/handle/10635/76676||ISSN:||09599428||DOI:||10.1039/c1jm14786b|
|Appears in Collections:||Staff Publications|
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