Please use this identifier to cite or link to this item: https://doi.org/10.1021/ol200538d
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dc.titleOne-pot synthesis of hybrid macrocyclic pentamers with variable functionalizations around the periphery
dc.contributor.authorQin, B.
dc.contributor.authorSun, C.
dc.contributor.authorLiu, Y.
dc.contributor.authorShen, J.
dc.contributor.authorYe, R.
dc.contributor.authorZhu, J.
dc.contributor.authorDuan, X.-F.
dc.contributor.authorZeng, H.
dc.date.accessioned2014-06-23T05:45:40Z
dc.date.available2014-06-23T05:45:40Z
dc.date.issued2011-05-06
dc.identifier.citationQin, B., Sun, C., Liu, Y., Shen, J., Ye, R., Zhu, J., Duan, X.-F., Zeng, H. (2011-05-06). One-pot synthesis of hybrid macrocyclic pentamers with variable functionalizations around the periphery. Organic Letters 13 (9) : 2270-2273. ScholarBank@NUS Repository. https://doi.org/10.1021/ol200538d
dc.identifier.issn15237060
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/76673
dc.description.abstractChemical equations presented. Rather than four- or six-residue macrocylces, one-pot macrocyclization allows for the highly selective formation of five-residue macrocycles rigidified by intramolecular hydrogen bonds. Variable functionalizations around the pentameric periphery were achieved by reacting monomers with higher oligomers bearing different exterior side chains. The formation of these hybrid pentamers suggests a chain-growth mechanism for the one-pot macrocyclization where the successive addition of monomers onto higher oligomers is faster than those between two monomers or two higher oligomers. © 2011 American Chemical Society.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/ol200538d
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1021/ol200538d
dc.description.sourcetitleOrganic Letters
dc.description.volume13
dc.description.issue9
dc.description.page2270-2273
dc.identifier.isiut000289956700033
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