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https://doi.org/10.1016/0957-4166(96)00210-8
DC Field | Value | |
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dc.title | NMR assignment of absolute configuration of a P-chiral diphosphine and mechanics of its stereoselective formation | |
dc.contributor.author | Aw, B.-H. | |
dc.contributor.author | Selvaratnam, S. | |
dc.contributor.author | Leung, P.-H. | |
dc.contributor.author | Rees, N.H. | |
dc.contributor.author | McFarlane, W. | |
dc.date.accessioned | 2014-06-23T05:45:16Z | |
dc.date.available | 2014-06-23T05:45:16Z | |
dc.date.issued | 1996-06 | |
dc.identifier.citation | Aw, B.-H., Selvaratnam, S., Leung, P.-H., Rees, N.H., McFarlane, W. (1996-06). NMR assignment of absolute configuration of a P-chiral diphosphine and mechanics of its stereoselective formation. Tetrahedron Asymmetry 7 (6) : 1753-1762. ScholarBank@NUS Repository. https://doi.org/10.1016/0957-4166(96)00210-8 | |
dc.identifier.issn | 09574166 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/76641 | |
dc.description.abstract | Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) NMR spectra are used to determine the absolute configuration of (+)-diphenyl- phosphine-2,3-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-2-ene. This diphosphine ligand is obtained from the palladium complex-promoted Diels- Alder reaction between diphenylvinylphosphine and 1-phenyl-3,3- dimethylphosphole in the presence of (R)-dimethyl(1-(α-naphthyl)ethylamine as the chiral auxiliary. The origin of the stereoselectivity in this asymmetric reaction is also revealed by solution NMR studies. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/0957-4166(96)00210-8 | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1016/0957-4166(96)00210-8 | |
dc.description.sourcetitle | Tetrahedron Asymmetry | |
dc.description.volume | 7 | |
dc.description.issue | 6 | |
dc.description.page | 1753-1762 | |
dc.description.coden | TASYE | |
dc.identifier.isiut | A1996UR37400037 | |
Appears in Collections: | Staff Publications |
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