Please use this identifier to cite or link to this item:
|Title:||Mesoions and ketene valence isomers. Pyrrolo[1,2-a]pyridinylium olates and (2-pyridyl)carbonylketenes||Authors:||Ye, X.
|Issue Date:||2000||Citation:||Ye, X.,Andraos, J.,Bibas, H.,Wong, M.W.,Wentrup, C. (2000). Mesoions and ketene valence isomers. Pyrrolo[1,2-a]pyridinylium olates and (2-pyridyl)carbonylketenes. Journal of the Chemical Society, Perkin Transactions 1 (3) : 401-406. ScholarBank@NUS Repository.||Abstract:||The zwitterionie title compounds 5a-d are obtained by FVT of picolinoylacetates 3a-d. Compounds 5a-d undergo nucleophilic addition reactions by C-N bond cleavage to afford pyridine derivatives 6-12. The thermal and photochemical ring opening of 5a to the ketene valence isomer 4a is demonstrated by matrix isolation IR spectroscopy and supported by excellent agreement with DFT calculations. © The Royal Society of Chemistry 2000.||Source Title:||Journal of the Chemical Society, Perkin Transactions 1||URI:||http://scholarbank.nus.edu.sg/handle/10635/76475||ISSN:||14704358|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jun 9, 2021
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.