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|Title:||Infinite Three-Dimensional Polymeric Metalloporphyrin Network via Six-Coordinate Zn(II) and Two Axial Oxygen Donors||Authors:||Teo, T.-L.
|Issue Date:||30-Oct-2003||Citation:||Teo, T.-L., Vetrichelvan, M., Lai, Y.-H. (2003-10-30). Infinite Three-Dimensional Polymeric Metalloporphyrin Network via Six-Coordinate Zn(II) and Two Axial Oxygen Donors. Organic Letters 5 (22) : 4207-4210. ScholarBank@NUS Repository. https://doi.org/10.1021/ol035665v||Abstract:||(Equation presented) An X-ray crystallographic study of zinc(II) 5,15-di-(2-methoxymethylphenyl)-porphyrin indicates that it forms a coordination polymer through ligation of the ether oxygen atoms on the porphyrin peripheries to the metal centers of two identical adjacent porphyrins. This gives a novel extensively linked, three-dimensional polymeric structure in which the zinc(II) metal forms a six-coordination center. The uniquely structured network has cavities between 4.81 and 9.27 Å, which makes it resemble molecular sieve materials.||Source Title:||Organic Letters||URI:||http://scholarbank.nus.edu.sg/handle/10635/76379||ISSN:||15237060||DOI:||10.1021/ol035665v|
|Appears in Collections:||Staff Publications|
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