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|Title:||Indium-mediated allylation of carbonyl compounds with an allylic bromide in aqueous media: Anomalous syn-diastereoselectivity regardless of allylic bromide geometry||Authors:||Loh, T.-P.
|Issue Date:||27-Jan-2003||Citation:||Loh, T.-P., Yin, Z., Song, H.-Y., Tan, K.-L. (2003-01-27). Indium-mediated allylation of carbonyl compounds with an allylic bromide in aqueous media: Anomalous syn-diastereoselectivity regardless of allylic bromide geometry. Tetrahedron Letters 44 (5) : 911-914. ScholarBank@NUS Repository. https://doi.org/10.1016/S0040-4039(02)02773-9||Abstract:||Anomalous syn-diastereoselectivity of indium-mediated coupling of aldehydes with bromides Z-3b and E-3b is reported. The reaction afforded high syn selectivity regardless of the allylic bromide geometry. Preliminary studies on the enantioselective indium-mediated allylation were attempted and found to give the desired products in moderate yield with high syn selectivity and enantioselectivity. © 2003 Elsevier Science Ltd. All rights reserved.||Source Title:||Tetrahedron Letters||URI:||http://scholarbank.nus.edu.sg/handle/10635/76371||ISSN:||00404039||DOI:||10.1016/S0040-4039(02)02773-9|
|Appears in Collections:||Staff Publications|
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