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Title: H-shaped oligothiophenes with low band gaps and amphoteric redox properties
Authors: Luo, J. 
Huang, K.-W.
Qu, H.
Zhang, X. 
Zhu, L.
Chan, H.S.O. 
Chi, C. 
Issue Date: 17-Dec-2010
Citation: Luo, J., Huang, K.-W., Qu, H., Zhang, X., Zhu, L., Chan, H.S.O., Chi, C. (2010-12-17). H-shaped oligothiophenes with low band gaps and amphoteric redox properties. Organic Letters 12 (24) : 5660-5663. ScholarBank@NUS Repository.
Abstract: H-shaped bridged oligothiophenes HT-1 and HT-2 were synthesized by two different approaches. Different from normal oligothiophenes, HT-1 and HT-2 showed low band gaps and amphoteric redox behaviors due to intramolecular charge transfer, which is further supported by time-dependent DFT calculations. © 2010 American Chemical Society.
Source Title: Organic Letters
ISSN: 15237060
DOI: 10.1021/ol102456c
Appears in Collections:Staff Publications

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