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https://doi.org/10.1166/jnn.2009.1342
Title: | Cross linking of gold nanoparticles with hexa-peri-hexabenzocoronene derivatives | Authors: | Vajiravelu, S. Ghosh, S. Valiyaveettil, S. |
Keywords: | Cyclotrimerisation Gold nanoparticles Hexa-peri-hexabenzocoronene Organic-inorganic nanohybrid Self-assembly |
Issue Date: | Nov-2009 | Citation: | Vajiravelu, S., Ghosh, S., Valiyaveettil, S. (2009-11). Cross linking of gold nanoparticles with hexa-peri-hexabenzocoronene derivatives. Journal of Nanoscience and Nanotechnology 9 (11) : 6587-6593. ScholarBank@NUS Repository. https://doi.org/10.1166/jnn.2009.1342 | Abstract: | The present investigation delineates the synthesis of hexa-peri- hexabenzocoronene capped gold nanoparticles. The coronene derivative has been synthesized by cyclotrimerisation of carbazole and thioanisole bearing alkyne to form 1,2,4-substituted isomer and coplanarised through a Scholl reaction. AuNP with 3-5 nm size and narrow distribution were synthesized using coronene derivative as the capping agent. The absorption and emission maximum of the coronene capped nanoparticles showed a hypsochromic shift of 10-15 nm as compared to the pristine coronene. The TEM images showed aggregated and well dispersed nanoparticles in which coronene molecules act as a bridge, leading to an inter particle distance of 1-2 nm. Copyright © 2009 American Scientific Publishers. | Source Title: | Journal of Nanoscience and Nanotechnology | URI: | http://scholarbank.nus.edu.sg/handle/10635/75836 | ISSN: | 15334880 | DOI: | 10.1166/jnn.2009.1342 |
Appears in Collections: | Staff Publications |
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