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https://doi.org/10.1063/1.1410388
| Title: | Covalent attachment of acetonitrile on Si(100) through Si-C and Si-N linkages | Authors: | Tao, F. Wang, Z.H. Qiao, M.H. Liu, Q. Sim, W.S. Xu, G.Q. |
Issue Date: | 8-Nov-2001 | Citation: | Tao, F., Wang, Z.H., Qiao, M.H., Liu, Q., Sim, W.S., Xu, G.Q. (2001-11-08). Covalent attachment of acetonitrile on Si(100) through Si-C and Si-N linkages. Journal of Chemical Physics 115 (18) : 8563-8569. ScholarBank@NUS Repository. https://doi.org/10.1063/1.1410388 | Abstract: | An analysis of covalent binding and adsorption states of acetonitrile on Si(100) was performed. For this analysis temperature programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS), high-resolution electron energy loss spectroscopy (HREELS) and density functional theory (DFT) were used. The results showed that acetonitrile chemisorbs on Si(100) in a side-on di-σ binding configuration forming Si-C and Si-N σ bonds. | Source Title: | Journal of Chemical Physics | URI: | http://scholarbank.nus.edu.sg/handle/10635/75831 | ISSN: | 00219606 | DOI: | 10.1063/1.1410388 |
| Appears in Collections: | Staff Publications |
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