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|Title:||Conformations of 1,2-dicyano-1,1,2,2-tetraphenylethane and cyanodiphenylmethyl peroxide||Authors:||Lam, Y.
|Issue Date:||Jun-2001||Citation:||Lam, Y., Lee, G.-H., Liang, E. (2001-06). Conformations of 1,2-dicyano-1,1,2,2-tetraphenylethane and cyanodiphenylmethyl peroxide. Bulletin of the Chemical Society of Japan 74 (6) : 1033-1034. ScholarBank@NUS Repository. https://doi.org/10.1246/bcsj.74.1033||Abstract:||The solid-state structures of 1,2-dicyano-1,1,2,2-tetraphenylethane and cyanodiphenylmethyl peroxide are determined by X-ray crystallography. Both molecules adopt the trans conformation in the solid-state. Experimentally derived values of the energy difference between the gauche and trans rotamers and their population quotient are compared with values predicted by semiempirical MO calculations.||Source Title:||Bulletin of the Chemical Society of Japan||URI:||http://scholarbank.nus.edu.sg/handle/10635/75806||ISSN:||00092673||DOI:||10.1246/bcsj.74.1033|
|Appears in Collections:||Staff Publications|
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