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|Title:||Asymmetric generation of fluorine-containing quaternary carbons adjacent to tertiary stereocenters: Uses of fluorinated methines as nucleophiles||Authors:||Han, X.
|Issue Date:||2009||Citation:||Han, X., Luo, J., Liu, C., Lu, Y. (2009). Asymmetric generation of fluorine-containing quaternary carbons adjacent to tertiary stereocenters: Uses of fluorinated methines as nucleophiles. Chemical Communications (15) : 2044-2046. ScholarBank@NUS Repository. https://doi.org/10.1039/b823184b||Abstract:||Organocatalytic asymmetric Michael reactions of fluorinated nucleophiles with nitroolefins catalyzed by Cinchona alkaloid-derived thiourea catalysts generated the desired Michael products containing vicinal fluorinated quaternary and tertiary chiral centers with exceptional enantioselectivity. © 2009 The Royal Society of Chemistry.||Source Title:||Chemical Communications||URI:||http://scholarbank.nus.edu.sg/handle/10635/75618||ISSN:||13597345||DOI:||10.1039/b823184b|
|Appears in Collections:||Staff Publications|
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