Please use this identifier to cite or link to this item:
Title: Alkoxy isothiocyanates, RO-N=C=S
Authors: Bech, A.T.
Flammang, R.
Pedersen, C.Th.
Wong, M.W. 
Wentrup, C.
Issue Date: Sep-1999
Citation: Bech, A.T.,Flammang, R.,Pedersen, C.Th.,Wong, M.W.,Wentrup, C. (1999-09). Alkoxy isothiocyanates, RO-N=C=S. Journal of the Chemical Society. Perkin Transactions 2 (9) : 1869-1873. ScholarBank@NUS Repository.
Abstract: Methoxy isothiocyanate has been identified as a product of pyrolysis of the silver salt of N-methoxydithiocarbamic acid. It is also formed on FVT of 1-(N-methoxythiocarbamoyl)imidazole and 1-(N-methoxythiocarbamoyl)-1,2,4-triazole. Methoxy isothiocyanate was identified by IR spectroscopy in argon matrices at 10 K supported by good agreement with the ab initio and DFT calculated spectrum. Isopropoxy isothiocyanate was generated from the corresponding silver salt in a similar manner. The oligomerization of MeONCS to trithiolanes and tetrathianes is also described.
Source Title: Journal of the Chemical Society. Perkin Transactions 2
ISSN: 03009580
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

checked on Mar 30, 2020

Google ScholarTM


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.