Please use this identifier to cite or link to this item:
|Title:||A simple route to a novel enantiomerically pure P-chiral phosphine ligand containing a tertiary amide functional group||Authors:||Leung, P.-H.
|Issue Date:||1996||Citation:||Leung, P.-H.,Loh, S.-K.,Mok, K.F.,White, A.J.P.,Williams, D.J. (1996). A simple route to a novel enantiomerically pure P-chiral phosphine ligand containing a tertiary amide functional group. Chemical Communications (5) : 591-592. ScholarBank@NUS Repository.||Abstract:||A new palladium(II) complex containing an amido-substituted P-chiral phosphine ligand is prepared efficiently by the asymmetric Diels-Alder reaction between N,N-dimethylacrylamide and 1-phenyl-3,4-dimethylphosphole; the chelating properties of the functionalised ligand and the absolute configurations of the four newly generated stereocentres are determined by single-crystal X-ray analysis, and the optically active phosphine ligand displaced from the palladium template with 1,2-bis(diphenylphosphino)ethane.||Source Title:||Chemical Communications||URI:||http://scholarbank.nus.edu.sg/handle/10635/75487||ISSN:||13597345|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jul 20, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.