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| Title: | A remote substituent as a control element in indium-mediated allylation reactions in aqueous media: Highly diastereoselective synthesis of 1,3-amino alcohols | Authors: | Loh, T.-P. Huang, J.-M. Xu, K.-C. Goh, S.-H. Vittal, J.J. |
Keywords: | 1,3-amino alcohols Allylation High diastereoselectivity Indium Remote substituent |
Issue Date: | 12-Aug-2000 | Citation: | Loh, T.-P.,Huang, J.-M.,Xu, K.-C.,Goh, S.-H.,Vittal, J.J. (2000-08-12). A remote substituent as a control element in indium-mediated allylation reactions in aqueous media: Highly diastereoselective synthesis of 1,3-amino alcohols. Tetrahedron Letters 41 (33) : 6511-6515. ScholarBank@NUS Repository. | Abstract: | A new method for the stereoselective synthesis of 1,3-amino alcohols based on the indium-mediated allylation of keto ester (R,S)-2 in aqueous media, resulting from shielding of one face by a remote substituent, was developed to be a useful method for acyclic stereocontrol in the absence of any obvious steric interaction. (C) 2000 Elsevier Science Ltd. | Source Title: | Tetrahedron Letters | URI: | http://scholarbank.nus.edu.sg/handle/10635/75480 | ISSN: | 00404039 |
| Appears in Collections: | Staff Publications |
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