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https://doi.org/10.1016/S0040-4039(03)01173-0
| Title: | A divergent approach to apoptolidin and FD-891: Asymmetric preparation of a common intermediate | Authors: | Chng, S.-S. Xu, J. Loh, T.-P. |
Keywords: | Apoptolidin Divergent synthesis FD-891 |
Issue Date: | 30-Jun-2003 | Citation: | Chng, S.-S., Xu, J., Loh, T.-P. (2003-06-30). A divergent approach to apoptolidin and FD-891: Asymmetric preparation of a common intermediate. Tetrahedron Letters 44 (27) : 4997-5000. ScholarBank@NUS Repository. https://doi.org/10.1016/S0040-4039(03)01173-0 | Abstract: | Biologically active Apoptolidin and FD-891 have structural similarity in their macrocyclic cores. Asymmetric preparation of a common intermediate in the total synthesis of these two macrolides is presented. A modified Masuyama Sn-allylation was employed to control the relative stereochemistry in the synthesis of the intermediate. © 2003 Elsevier Science Ltd. All rights reserved. | Source Title: | Tetrahedron Letters | URI: | http://scholarbank.nus.edu.sg/handle/10635/75408 | ISSN: | 00404039 | DOI: | 10.1016/S0040-4039(03)01173-0 |
| Appears in Collections: | Staff Publications |
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