Please use this identifier to cite or link to this item: https://doi.org/10.1002/chir.530040308
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dc.titleChromatographic resolution of the chiral isomers of several β-blockers over cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase
dc.contributor.authorChing, C.B.
dc.contributor.authorLim, B.G.
dc.contributor.authorLee, E.J.D.
dc.contributor.authorNg, S.C.
dc.date.accessioned2014-06-17T10:00:46Z
dc.date.available2014-06-17T10:00:46Z
dc.date.issued1992
dc.identifier.citationChing, C.B., Lim, B.G., Lee, E.J.D., Ng, S.C. (1992). Chromatographic resolution of the chiral isomers of several β-blockers over cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase. Chirality 4 (3) : 174-177. ScholarBank@NUS Repository. https://doi.org/10.1002/chir.530040308
dc.identifier.issn08990042
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/67384
dc.description.abstractThe optical resolution of seven β-blockers which have in common the N- isopropyl-3-aryloxy-2-hydroxypropylamine moiety was carried out by HPLC using the cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase to quantitatively characterize the enantioselectivity of these compounds. The capacity factors and separation factors at different column temperature were determined with some qualitative trends derived. A compensation effect was observed for these compounds where there exists an approximately linear relationship between the enantiomeric differences in enthalpic and entropic energies.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/chir.530040308
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMICAL ENGINEERING
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1002/chir.530040308
dc.description.sourcetitleChirality
dc.description.volume4
dc.description.issue3
dc.description.page174-177
dc.description.codenCHRLE
dc.identifier.isiutA1992HU95700007
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