Please use this identifier to cite or link to this item: https://doi.org/10.1002/1521-3935(20010101)202:1<31
DC FieldValue
dc.titleSpecific interactions in miscible poly(p-vinylphenol)/poly(N-methyl-3-piperidinemethyl methacrylate) blends
dc.contributor.authorGoh, S.H.
dc.contributor.authorLee, S.Y.
dc.contributor.authorLuo, X.
dc.contributor.authorWong, M.W.
dc.contributor.authorTan, K.L.
dc.date.accessioned2014-05-19T02:55:20Z
dc.date.available2014-05-19T02:55:20Z
dc.date.issued2001-01-24
dc.identifier.citationGoh, S.H.,Lee, S.Y.,Luo, X.,Wong, M.W.,Tan, K.L. (2001-01-24). Specific interactions in miscible poly(p-vinylphenol)/poly(N-methyl-3-piperidinemethyl methacrylate) blends. Macromolecular Chemistry and Physics 202 (1) : 31-35. ScholarBank@NUS Repository. <a href="https://doi.org/10.1002/1521-3935(20010101)202:1<31" target="_blank">https://doi.org/10.1002/1521-3935(20010101)202:1<31</a>
dc.identifier.issn10221352
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/53184
dc.description.abstractPoly(p-vinylphenol) (PVPh) is miscible with poly(N-methyl-3-piperidinemethyl methacrylate) (PM3PMA). The glass transition temperatures of the blends are higher than those calculated from a linear additivity rule. Fourier transform infrared spectroscopy shows the existence of hydrogen-bonding interactions between the hydroxyl groups of PVPh and the carbonyl groups of PM3PMA. In addition, X-ray photoelectron spectroscopy shows that the piperidine nitrogen atoms of PM3PMA also interact with the hydroxyl groups of PVPh as shown by the development of a high-binding energy N 1s peak in each blend. In contrast, we have earlier reported that the piperidine nitrogen atoms of poly(N-methyl-4-piperidyl methacrylate) are not involved in hydrogen-bonding interactions with PVPh. To better understand the interactions in various blends, ab initio calculations were performed on hyrdrogen-bonded dimers of saturated monomers.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/1521-3935(20010101)202:1<31
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.contributor.departmentPHYSICS
dc.description.doi10.1002/1521-3935(20010101)202:1<31
dc.description.sourcetitleMacromolecular Chemistry and Physics
dc.description.volume202
dc.description.issue1
dc.description.page31-35
dc.description.codenMCHPE
dc.identifier.isiut000166767600006
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