Please use this identifier to cite or link to this item: https://doi.org/10.1002/chem.201302600
DC FieldValue
dc.titleAngular-Resolved Magnetometry Beyond Triclinic Crystals: Out-of-Equilibrium Studies of Cp*ErCOT Single-Molecule Magnet
dc.contributor.authorBoulon, Marie-Emmanuelle
dc.contributor.authorCucinotta, Giuseppe
dc.contributor.authorLiu, Shan-Shan
dc.contributor.authorJiang, Shang-Da
dc.contributor.authorUngur, Liviu
dc.contributor.authorChibotaru, Liviu F
dc.contributor.authorGao, Song
dc.contributor.authorSessoli, Roberta
dc.date.accessioned2022-07-19T09:25:36Z
dc.date.available2022-07-19T09:25:36Z
dc.date.issued2013-10-04
dc.identifier.citationBoulon, Marie-Emmanuelle, Cucinotta, Giuseppe, Liu, Shan-Shan, Jiang, Shang-Da, Ungur, Liviu, Chibotaru, Liviu F, Gao, Song, Sessoli, Roberta (2013-10-04). Angular-Resolved Magnetometry Beyond Triclinic Crystals: Out-of-Equilibrium Studies of Cp*ErCOT Single-Molecule Magnet. CHEMISTRY-A EUROPEAN JOURNAL 19 (41) : 13726-13731. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201302600
dc.identifier.issn09476539
dc.identifier.issn15213765
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228828
dc.description.abstractAngular-resolved single-crystal magnetometry is a key tool to characterise lanthanide-based materials with low symmetry, for which conjectures based on idealised geometries can be totally misleading. Unfortunately the technique is strictly successful only for triclinic structures, thus reducing significantly its application. By collecting out-of-equilibrium magnetisation data the technique was extended to the orthorhombic organometallic Cp*ErCOT single-molecule magnet (SMM), thus allowing for the first time the reconstruction of the molecular anisotropy tensor notwithstanding the two molecular orientations in the crystal lattice. The results, flanked by state-of-the-art ab initio calculations, confirmed the expected orientation of the molecular easy axis of magnetisation and thus validated the synthetic strategy based on organometallic complexes of a single lanthanide ion. From crystal to molecule: Angular-resolved magnetometry on single crystals, a powerful tool to investigate magnetic anisotropy, has been extended to non-triclinic single-molecule magnets (i.e., those that contain more than one orientation of the molecules in the crystal) by exploiting the reconstruction of the molecular anisotropy tensor from out-of-equilibrium magnetization data (see figure). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.language.isoen
dc.publisherWILEY-V C H VERLAG GMBH
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Multidisciplinary
dc.subjectChemistry
dc.subjectab initio calculations
dc.subjectanisotropy
dc.subjectlanthanides
dc.subjectmagnetic properties
dc.subjectmolecular design
dc.subjectGROUND-STATE
dc.subjectSPIN
dc.subjectANISOTROPY
dc.subjectLANTHANIDES
dc.subjectCOMPLEXES
dc.subjectDESIGN
dc.subjectSERIES
dc.typeArticle
dc.date.updated2022-07-15T01:50:09Z
dc.contributor.departmentDEPT OF CHEMISTRY
dc.description.doi10.1002/chem.201302600
dc.description.sourcetitleCHEMISTRY-A EUROPEAN JOURNAL
dc.description.volume19
dc.description.issue41
dc.description.page13726-13731
dc.published.statePublished
Appears in Collections:Staff Publications
Elements

Show simple item record
Files in This Item:
File Description SizeFormatAccess SettingsVersion 
Boulon_CEJ_2013.pdfPublished version739.37 kBAdobe PDF

CLOSED

None
Boulon_CEJ_2013_SI.pdfSupporting information894.1 kBAdobe PDF

CLOSED

None

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.