Please use this identifier to cite or link to this item:
https://doi.org/10.1002/chem.201302600
DC Field | Value | |
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dc.title | Angular-Resolved Magnetometry Beyond Triclinic Crystals: Out-of-Equilibrium Studies of Cp*ErCOT Single-Molecule Magnet | |
dc.contributor.author | Boulon, Marie-Emmanuelle | |
dc.contributor.author | Cucinotta, Giuseppe | |
dc.contributor.author | Liu, Shan-Shan | |
dc.contributor.author | Jiang, Shang-Da | |
dc.contributor.author | Ungur, Liviu | |
dc.contributor.author | Chibotaru, Liviu F | |
dc.contributor.author | Gao, Song | |
dc.contributor.author | Sessoli, Roberta | |
dc.date.accessioned | 2022-07-19T09:25:36Z | |
dc.date.available | 2022-07-19T09:25:36Z | |
dc.date.issued | 2013-10-04 | |
dc.identifier.citation | Boulon, Marie-Emmanuelle, Cucinotta, Giuseppe, Liu, Shan-Shan, Jiang, Shang-Da, Ungur, Liviu, Chibotaru, Liviu F, Gao, Song, Sessoli, Roberta (2013-10-04). Angular-Resolved Magnetometry Beyond Triclinic Crystals: Out-of-Equilibrium Studies of Cp*ErCOT Single-Molecule Magnet. CHEMISTRY-A EUROPEAN JOURNAL 19 (41) : 13726-13731. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201302600 | |
dc.identifier.issn | 09476539 | |
dc.identifier.issn | 15213765 | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/228828 | |
dc.description.abstract | Angular-resolved single-crystal magnetometry is a key tool to characterise lanthanide-based materials with low symmetry, for which conjectures based on idealised geometries can be totally misleading. Unfortunately the technique is strictly successful only for triclinic structures, thus reducing significantly its application. By collecting out-of-equilibrium magnetisation data the technique was extended to the orthorhombic organometallic Cp*ErCOT single-molecule magnet (SMM), thus allowing for the first time the reconstruction of the molecular anisotropy tensor notwithstanding the two molecular orientations in the crystal lattice. The results, flanked by state-of-the-art ab initio calculations, confirmed the expected orientation of the molecular easy axis of magnetisation and thus validated the synthetic strategy based on organometallic complexes of a single lanthanide ion. From crystal to molecule: Angular-resolved magnetometry on single crystals, a powerful tool to investigate magnetic anisotropy, has been extended to non-triclinic single-molecule magnets (i.e., those that contain more than one orientation of the molecules in the crystal) by exploiting the reconstruction of the molecular anisotropy tensor from out-of-equilibrium magnetization data (see figure). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | |
dc.language.iso | en | |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.source | Elements | |
dc.subject | Science & Technology | |
dc.subject | Physical Sciences | |
dc.subject | Chemistry, Multidisciplinary | |
dc.subject | Chemistry | |
dc.subject | ab initio calculations | |
dc.subject | anisotropy | |
dc.subject | lanthanides | |
dc.subject | magnetic properties | |
dc.subject | molecular design | |
dc.subject | GROUND-STATE | |
dc.subject | SPIN | |
dc.subject | ANISOTROPY | |
dc.subject | LANTHANIDES | |
dc.subject | COMPLEXES | |
dc.subject | DESIGN | |
dc.subject | SERIES | |
dc.type | Article | |
dc.date.updated | 2022-07-15T01:50:09Z | |
dc.contributor.department | DEPT OF CHEMISTRY | |
dc.description.doi | 10.1002/chem.201302600 | |
dc.description.sourcetitle | CHEMISTRY-A EUROPEAN JOURNAL | |
dc.description.volume | 19 | |
dc.description.issue | 41 | |
dc.description.page | 13726-13731 | |
dc.published.state | Published | |
Appears in Collections: | Staff Publications Elements |
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File | Description | Size | Format | Access Settings | Version | |
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Boulon_CEJ_2013.pdf | Published version | 739.37 kB | Adobe PDF | CLOSED | None | |
Boulon_CEJ_2013_SI.pdf | Supporting information | 894.1 kB | Adobe PDF | CLOSED | None |
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