Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201206602
Title: Coupling Dy-3 Triangles to Maximize the Toroidal Moment
Authors: Lin, Shuang-Yan
Wernsdorfer, Wolfgang
Ungur, Liviu 
Powell, Annie K
Guo, Yun-Nan
Tang, Jinkui
Zhao, Lang
Chibotaru, Liviu F
Zhang, Hong-Jie
Keywords: Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
ab initio calculations
dysprosium
non-magnetic doublet
single-molecule magnets
toroidal moment
SINGLE-MOLECULE-MAGNET
SOLID-STATE PHYSICS
DYSPROSIUM TRIANGLES
GROUND-STATE
BEHAVIOR
RELAXATION
MAGNETIZATION
DYNAMICS
COMPLEX
LIGAND
Issue Date: 1-Jan-2012
Publisher: WILEY-V C H VERLAG GMBH
Citation: Lin, Shuang-Yan, Wernsdorfer, Wolfgang, Ungur, Liviu, Powell, Annie K, Guo, Yun-Nan, Tang, Jinkui, Zhao, Lang, Chibotaru, Liviu F, Zhang, Hong-Jie (2012-01-01). Coupling Dy-3 Triangles to Maximize the Toroidal Moment. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 51 (51) : 12767-12771. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201206602
Abstract: A hexanuclear dysprosium(III) compound constructed by two Dy3 triangles in an edge-to-edge arrangement perfectly retains a nonmagnetic ground state and single-molecular-magnet behavior. Such an arrangement and the strong couplings over a μ4-O2- ion stabilize a similar arrangement of toroidal moments in the ground state, thus maximizing the toroidal moment of the complex. (Picture: Dy purple, C gray, N blue, O red.) Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
URI: https://scholarbank.nus.edu.sg/handle/10635/228787
ISSN: 14337851
15213773
DOI: 10.1002/anie.201206602
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