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https://doi.org/10.1002/anie.201206602
| Title: | Coupling Dy-3 Triangles to Maximize the Toroidal Moment | Authors: | Lin, Shuang-Yan Wernsdorfer, Wolfgang Ungur, Liviu Powell, Annie K Guo, Yun-Nan Tang, Jinkui Zhao, Lang Chibotaru, Liviu F Zhang, Hong-Jie |
Keywords: | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry ab initio calculations dysprosium non-magnetic doublet single-molecule magnets toroidal moment SINGLE-MOLECULE-MAGNET SOLID-STATE PHYSICS DYSPROSIUM TRIANGLES GROUND-STATE BEHAVIOR RELAXATION MAGNETIZATION DYNAMICS COMPLEX LIGAND |
Issue Date: | 1-Jan-2012 | Publisher: | WILEY-V C H VERLAG GMBH | Citation: | Lin, Shuang-Yan, Wernsdorfer, Wolfgang, Ungur, Liviu, Powell, Annie K, Guo, Yun-Nan, Tang, Jinkui, Zhao, Lang, Chibotaru, Liviu F, Zhang, Hong-Jie (2012-01-01). Coupling Dy-3 Triangles to Maximize the Toroidal Moment. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 51 (51) : 12767-12771. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201206602 | Abstract: | A hexanuclear dysprosium(III) compound constructed by two Dy3 triangles in an edge-to-edge arrangement perfectly retains a nonmagnetic ground state and single-molecular-magnet behavior. Such an arrangement and the strong couplings over a μ4-O2- ion stabilize a similar arrangement of toroidal moments in the ground state, thus maximizing the toroidal moment of the complex. (Picture: Dy purple, C gray, N blue, O red.) Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | Source Title: | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | URI: | https://scholarbank.nus.edu.sg/handle/10635/228787 | ISSN: | 14337851 15213773 |
DOI: | 10.1002/anie.201206602 |
| Appears in Collections: | Staff Publications Elements |
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| File | Description | Size | Format | Access Settings | Version | |
|---|---|---|---|---|---|---|
| Lin_Angew_2012.cif.txt | Supporting information | 41.38 kB | Text | CLOSED | None | |
| Lin_Angew_2012.pdf | Published version | 709.85 kB | Adobe PDF | CLOSED | None | |
| Lin_Angew_2012_SI.pdf | Supporting information | 798.92 kB | Adobe PDF | CLOSED | None |
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