Please use this identifier to cite or link to this item: https://doi.org/10.1002/ejic.201100038
Title: A Rare mu(4)-O Centred Dy-4 Tetrahedron with Coordination-Induced Local Chirality and Single-Molecule Magnet Behaviour
Authors: Lin, Po-Heng
Korobkov, Ilia
Wernsdorfer, Wolfgang
Ungur, Liviu 
Chibotaru, Liviu F
Murugesu, Muralee
Keywords: Science & Technology
Physical Sciences
Chemistry, Inorganic & Nuclear
Chemistry
Clusters
Magnetic properties
Single-molecule magnets
Chirality
Lanthanides
SPONTANEOUS RESOLUTION
DYSPROSIUM TRIANGLES
WEAK FERROMAGNETISM
ANISOTROPIC BARRIER
SLOW RELAXATION
GROUND-STATE
COMPLEXES
SPIN
LIGANDS
CLUSTERS
Issue Date: 1-Apr-2011
Publisher: WILEY-V C H VERLAG GMBH
Citation: Lin, Po-Heng, Korobkov, Ilia, Wernsdorfer, Wolfgang, Ungur, Liviu, Chibotaru, Liviu F, Murugesu, Muralee (2011-04-01). A Rare mu(4)-O Centred Dy-4 Tetrahedron with Coordination-Induced Local Chirality and Single-Molecule Magnet Behaviour. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2011 (10) : 1535-1539. ScholarBank@NUS Repository. https://doi.org/10.1002/ejic.201100038
Abstract: Coordination-induced chirality was achieved in a uniquetetrahedral [Dy 4(μ4-O)(μ-OMe)2(beh)2(esh) 4]·3MeOH complex through a twisted diazine bridge from a Schiff base ligand. Magnetic measurements reveal weak intramolecular antiferromagnetic interactions (J = -0.3 cm-1) with single-molecule magnet behaviour (Ueff = 23.42 K). Coordination-induced chirality was achieved in a unique tetrahedral [Dy4(μ4-O)(μ-OMe) 2(beh)2(esh)4]·3MeOH complex through a twisted diazine bridge from a Schiff base ligand. Magnetic measurementsreveal weak intramolecular antiferromagnetic interactions (J = -0.3 cm-1) with single-molecule magnet behaviour (Ueff = 23.42 K). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA.
Source Title: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
URI: https://scholarbank.nus.edu.sg/handle/10635/228759
ISSN: 14341948
10990682
DOI: 10.1002/ejic.201100038
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