Please use this identifier to cite or link to this item: https://doi.org/10.1039/c6sc00318d
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dc.titleMultitechnique investigation of Dy3-implications for coupled lanthanide clusters
dc.contributor.authorGysler, Maren
dc.contributor.authorEl Hallak, Fadi
dc.contributor.authorUngur, Liviu
dc.contributor.authorMarx, Raphael
dc.contributor.authorHakl, Michael
dc.contributor.authorNeugebauer, Petr
dc.contributor.authorRechkemmer, Yvonne
dc.contributor.authorLan, Yanhua
dc.contributor.authorSheikin, Ilya
dc.contributor.authorOrlita, Milan
dc.contributor.authorAnson, Christopher E
dc.contributor.authorPowell, Annie K
dc.contributor.authorSessoli, Roberta
dc.contributor.authorChibotaru, Liviu F
dc.contributor.authorvan Slageren, Joris
dc.date.accessioned2022-07-17T14:13:22Z
dc.date.available2022-07-17T14:13:22Z
dc.date.issued2016-01-01
dc.identifier.citationGysler, Maren, El Hallak, Fadi, Ungur, Liviu, Marx, Raphael, Hakl, Michael, Neugebauer, Petr, Rechkemmer, Yvonne, Lan, Yanhua, Sheikin, Ilya, Orlita, Milan, Anson, Christopher E, Powell, Annie K, Sessoli, Roberta, Chibotaru, Liviu F, van Slageren, Joris (2016-01-01). Multitechnique investigation of Dy3-implications for coupled lanthanide clusters. CHEMICAL SCIENCE 7 (7) : 4347-4354. ScholarBank@NUS Repository. https://doi.org/10.1039/c6sc00318d
dc.identifier.issn2041-6520
dc.identifier.issn2041-6539
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228725
dc.description.abstractIn-depth investigations of the low energy electronic structures of mononuclear lanthanide complexes, including single molecule magnets, are challenging at the best of times. For magnetically coupled polynuclear systems, the task seems well nigh impossible. However, without detailed understanding of the electronic structure, there is no hope of understanding their static and dynamic magnetic properties in detail. We have been interested in assessing which techniques are most appropriate for studying lanthanide single-molecule magnets. Here we present a wide ranging theoretical and experimental study of the archetypal polynuclear lanthanide single-molecule magnet Dy3 and derive the simplest model to describe the results from each experimental method, including high-frequency electron paramagnetic resonance and far-infrared spectroscopies and cantilever torque magnetometry. We conclude that a combination of these methods together with ab initio calculations is required to arrive at a full understanding of the properties of this complex, and potentially of other magnetically coupled lanthanide complexes.
dc.language.isoen
dc.publisherROYAL SOC CHEMISTRY
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Multidisciplinary
dc.subjectChemistry
dc.subjectSINGLE-MOLECULE MAGNETS
dc.subjectSPECTROSCOPIC DETERMINATION
dc.subjectDYSPROSIUM TRIANGLES
dc.subjectTORQUE MAGNETOMETRY
dc.subjectANISOTROPY
dc.subjectBEHAVIOR
dc.typeArticle
dc.date.updated2022-07-15T02:37:52Z
dc.contributor.departmentDEPT OF CHEMISTRY
dc.description.doi10.1039/c6sc00318d
dc.description.sourcetitleCHEMICAL SCIENCE
dc.description.volume7
dc.description.issue7
dc.description.page4347-4354
dc.published.statePublished
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