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Please use this identifier to cite or link to this item: https://doi.org/10.1021/acs.joc.8b00953
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dc.titleGold-Catalyzed Post-Ugi Ipso-Cyclization with Switchable Diastereoselectivity
dc.contributor.authorNechaev, Anton A
dc.contributor.authorVan Hecke, Kristof
dc.contributor.authorZaman, Manzoor
dc.contributor.authorKashtanov, Stepan
dc.contributor.authorUngur, Liviu
dc.contributor.authorPereshivko, Olga P
dc.contributor.authorPeshkov, Vsevolod A
dc.contributor.authorVan der Eycken, Erik V
dc.date.accessioned2022-07-15T08:42:39Z
dc.date.available2022-07-15T08:42:39Z
dc.date.issued2018-08-03
dc.identifier.citationNechaev, Anton A, Van Hecke, Kristof, Zaman, Manzoor, Kashtanov, Stepan, Ungur, Liviu, Pereshivko, Olga P, Peshkov, Vsevolod A, Van der Eycken, Erik V (2018-08-03). Gold-Catalyzed Post-Ugi Ipso-Cyclization with Switchable Diastereoselectivity. JOURNAL OF ORGANIC CHEMISTRY 83 (15) : 8170-8182. ScholarBank@NUS Repository. https://doi.org/10.1021/acs.joc.8b00953
dc.identifier.issn00223263
dc.identifier.issn15206904
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228695
dc.description.abstractA gold-catalyzed post-Ugi ipso-cyclization for the diastereoselective synthesis of spirocyclic pyrrol-2-one-dienone system is described. Tuning the catalytic system, solvent, and temperature allowed selectively attaining two sets of diastereoisomers. The scope of the process has been evaluated, and a putative mechanistic model was proposed.
dc.language.isoen
dc.publisherAMER CHEMICAL SOC
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Organic
dc.subjectChemistry
dc.subjectMICHAEL CASCADE REACTION
dc.subjectN-ARYL ALKYNAMIDES
dc.subjectONE-POT SYNTHESIS
dc.subjectINTRAMOLECULAR HYDROARYLATION
dc.subjectSELECTIVE SYNTHESIS
dc.subjectPASSERINI REACTIONS
dc.subjectBETA-LACTAMS
dc.subjectDEAROMATIZATION
dc.subjectTRANSFORMATIONS
dc.subjectCONSTRUCTION
dc.typeArticle
dc.date.updated2022-07-15T02:54:01Z
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1021/acs.joc.8b00953
dc.description.sourcetitleJOURNAL OF ORGANIC CHEMISTRY
dc.description.volume83
dc.description.issue15
dc.description.page8170-8182
dc.published.statePublished
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